He is a Professor/Senior Research Fellow at the Centre for Advancement of Scholarship, University of Pretoria; Co-Chair of the UN Working Group on the Guiding Principles for Responsible Sovereign Borrowing and Lending; Senior Non-Resident Fellow, Global Development Policy Center, Boston University; and Professor Emeritus, American University Washington College of Law.

Daniel was previously the South African Research Chair Initiative (SARCHI) Professor of International Development Law and African Economic Relations at the Centre for Human Rights, University of Pretoria. He has also served as Head of the International Economic Relations and Policy Department of the South African Reserve Bank, Chair of the Roster of Experts for the Independent Review Mechanism of the African Development Bank, and consultant to numerous international organisations.